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李忠原 博士,副教授,硕士生导师 邮箱: zhongyuanli@ahnu.edu.cn 实验室: 学苑南楼五号楼 417
办公室: 学苑南楼五号楼 414
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♦ 学习工作经历
2021.10 - 至今 安徽师范大学
2020.04 - 2021.08 美国密西根大学,博士后 (with Prof. Nathaniel K. Szymczak and Prof. Corey Stephenson)
2018.06 - 2020.03 美国密西西比州立大学,博士后 (with Prof. Xin Cui)
2012.09 - 2017.06 中国科学技术大学,博士(导师:王官武教授)
2008.09 - 2012.07 安徽师范大学,学士(指导老师:郝二红教授)
♦ 研究兴趣
过渡金属催化碳氢活化
不对称催化
手性功能分子设计和合成
♦ 项目基金
国家自然科学基金青年基金(2023.01-2025.12)
安徽省高校自然科学基金重点项目(2021.12-2023.12)
安徽师范大学启动基金(2021.12-2024.12)
♦课题组成员
研究生
2023级博士生 2021级硕士生 2022级硕士生 2023级硕士生
张金萍 刘芳 侯富成 杨洁莹 马娟 熊浦东 张雪晴 张家乐
本科生
2022级
吕胡艳 杜雅茹 王甜甜 付然然 唐婉婉 程富强
♦课题组毕业生
研究生
2020级硕士
张金萍
本科生
2019级 2020级
刘柱 刘吉涛 应允义 王梓瑞 徐加快 柴思妮 左博文
♦ 代表性论文
2021年以后发表文章
18. Fu-Cheng Hou, Jia-Le Zhang, Zi-Rui Wang and Zhong-Yuan Li*. "Rhodium-catalyzed three-component C(sp3)/C(sp2)–H activation enabled by a two-fold directing group strategy" Chem. Commun. 2024, 60, 5634-5637.
17. Long Wang, Cheng Cheng, Zhong-Yuan Li*, Xing Guo, Qinghua Wu*, Erhong Hao, and Lijuan Jiao*. "Nucleophilic Aromatic Substitution (SNAr) as an Approach to Challenging Nitrogen-Bridged BODIPY Oligomers" Org. Lett. 2024, 26, 3026-3031.
16. Zhong-Yuan Li*, Fang Liu, Heng Li, Xing Guo, Lijuan Jiao, and Erhong Hao*. "Rhodium-Catalyzed Two-Fold, Regioselective and Enantioselective C–H Activation: an Efficient Strategy to Chiral Single-Benzene-Based Fluorophores" Org. Lett. 2024, 26, 444–449.
15. Dandan Wang, Long Wang, Xing Guo, Xiankang Zhang, Juan Ma, Zhengxin Kang, Zhong-Yuan Li*, Lijuan Jiao*, and Erhong Hao*. "Visible-Light-Induced Direct Photoamination of BODIPY Dyes with Aqueous Ammonia" Org. Lett. 2023, 25, 7650–7655.
14. Fan Lv, Xing Guo, Zhong-Yuan Li *, Qinghua Wu, Juanjie Chen, Changjiang Yu, Lijuan Jiao*, Erhong Hao*. "Copper-catalyzed α-selective cross-dehydrogenative coupling of BODIPY dyes with aldehydes: A new route to acylated BODIPYs and dipyrromethenes" Dyes Pigments 2023, 210, 111030.
13. Zhong-Yuan Li*, Jin-Ping Zhang, Yun-Yi Ying, Dong Yan, Lijuan Jiao, and Erhong Hao*. "Rhodium-Catalyzed Tandem C–H Annulation Enabled by Transient Directing Group Strategy and Sequential Nucleophilic Substitution" Org. Lett. 2022, 24, 7888-7893.
12. Xinyue Wu, Guoyong Xu, Weiqing Lu, Zhong-Yuan Li*, Shengyu Dai*.“Ethylene (Co)oligomerization in Alkane Solvents Facilitated by Rigid-flexible Double-layer Steric Strategy” Eur. Polym. J. 2022, 177, 111459.
Before AHNU
11. Alex M. Davies, Zhong-Yuan Li, Corey R. J. Stephenson*, and Nathaniel K. Szymczak*.“Valorization of Ethanol: Ruthenium-Catalyzed Guerbet and Sequential Functionalization Processes” ACS Catal. 2022, 12, 6729–6736.
10. Zhong-Yuan Li, Hetti Handi Chaminda Lakmal, Xiaolin Qian, Zhenyu Zhu, Bruno Donnadieu, Sarah J. McClain, Xue Xu, and Xin Cui*. “Ruthenium-Catalyzed Enantioselective C–H Functionalization: A Practical Access to Optically Active Indoline Derivatives” J. Am. Chem. Soc. 2019, 141, 15730−15736. (highlighted by Synfacts)
9. Zhong-Yuan Li, Hetti Handi Chaminda Lakmal, Xin Cui*. “Enabling Catalytic Arene C–H Amidomethylation via Bis(tosylamido)methane as a Sustainable Formaldimine Releaser” Org. Lett. 2019, 21, 3735−3740.
8. Zhong-Yuan Li, Kun Jing, Qi-Li Li, and Guan-Wu Wang*. “Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with 2-Aryloxypyridines” Acta. Chim. Sinica. 2019, 77, 729−734.
7. Zhong-Yuan Li, Liang Li, Qi-Li Li, Kun Jing, Hui Xu, and Guan-Wu Wang*. “Ruthenium-Catalyzed meta-Selective C–H Mono- and Difluoromethylation of Arenes through ortho-Metalation Strategy” Chem. Eur. J. 2017, 23, 3285–3290.
6. Zhong-Yuan Li, and Guan-Wu Wang*. “Palladium-Catalyzed Decarboxylative Ortho-Ethoxycarbonylation of O Methyl Ketoximes and 2 Arylpyridines with Potassium Oxalate Monoester” Org. Lett. 2015, 17, 4866−4869.
5. Zhong-Yuan Li, Dan-Dan Li, and Guan-Wu Wang*. “Palladium-Catalyzed Decarboxylative Ortho Acylation of Azobenzenes with α Oxocarboxylic Acids” J. Org. Chem. 2013, 78, 10414–10420.
4. Kun Jing, Zhong-Yuan Li, and Guan-Wu Wang*. “Direct Decarboxylative Meta-Selective Acylation of Arenes via an Ortho-Ruthenation Strategy” ACS Catal. 2018, 8, 11875−11881.
3. Qi-Li Li, Zhong-Yuan Li, Guan-Wu Wang*. “Palladium-Catalyzed Decarboxylative ortho-Acylation of Anilines with Carbamate as a Removable Directing Group” ACS Omega 2018, 3, 4187−4198.
2. Kun Jing, Jia-Ping Yao, Zhong-Yuan Li, Qi-Li Li, Hao-Sheng Lin, Guan-Wu Wang*. “Palladium-Catalyzed Decarboxylative ortho-Acylation of Benzamides with α-Oxocarboxylic Acids” J. Org. Chem. 2017, 82, 12715–12725.
1. Dan-Dan Li, Zhong-Yuan Li, Guan-Wu Wang*. “A Catalyst-Free Approach to Construct C−C Bond Initiated by N−O Bond Cleavage under Thermal Heating Conditions” J. Org. Chem. 2015, 80, 190−195.